I would think you could catch six before midnight and six after, the former being your creel limit for the first day and the latter being your creel/possession limit. Course I don't know how you would put a time stamp on them to prove what time you caught them!!
As far as Pymatuning and keeping six for your Ohio License and Six for your Pa license, I would say that would be a big NO. The ability to use either license is an agreement between the two states to extend the courtesy to fisherman to avoid having to buy an out of state license. The law that allows six walleyes is for the Lake of Pymatuning, not for the license of the state you are from! The body of water carries the restrictions or allowances, i.e. size, number, open or closed seasons..not the license. The license merely permits you to fish a body of water