HT in my younger days, I remember mountains of "cinders" stockpiled at various township locations. The cinders would be collected from school buildings, hospitals, industry, etc. until needed for winter road maintenance. In some areas, salt and 'shot' would be mixed and spread.
Today, as we know, mostly salt or calcium chloride is used which ain't worth a crap when the road surface temps hit single numbers.
As for pretreating, I never saw any good from it, if & when there was a continuous snowfall or temps. continued to fall below the effective threshold.
More times then not, the initial snow melts, allowing for ice to form beneath the continued snowfall.
Love them PENNDOT Supervisors standing in front of the cameras boasting "we've pretreated the roads" in anticipation of the storm.
I'd much rather hear, "we've got the state employees sitting in their equipment so we can "plow with the storm".